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on digestate humification and identification of substances governing the dissolved organic matter (DOM) transformation process

《环境科学与工程前沿（英文）》 2022年 第16卷 第8期 doi: 10.1007/s11783-022-1520-0

摘要：

• Liquid digestate humification was investigated under different oxidizing environment.

关键词： Liquid digestate     MnO2     Oxygen     DOM transformation     Humic-like acids    

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Quantitative characterization of Cu binding potential of dissolved organic matter (DOM) in sediment from

Yuan ZHANG,Yan ZHANG,Tao YU

《环境科学与工程前沿（英文）》 2014年 第8卷 第5期   页码 666-674 doi: 10.1007/s11783-013-0608-y

摘要： Dissolved organic matter (DOM) plays an important role in heavy metal speciation and distribution in the aquatic environment especially for eutrophic lakes which have higher DOM concentration. Taihu Lake is the third largest freshwater and a high eutrophic lake in the downstream of the Yangtze River, China. In the lake, frequent breakout of algae blooms greatly increased the concentration of different organic matters in the lake sediment. In this study, sediment samples were collected from various part of Taihu Lake to explore the spatial difference in the binding potential of DOM with Cu. The titration experiment was adopted to quantitatively characterize the interaction between Cu(II) and DOM extracted from Taihu Lake sediments using ion selective electrode (ISE) and fluorescence quenching technology. The ISE results showed that the exogenous DOM had higher binding ability than endogenous DOM, and DOM derived from aquatic macrophytes had a higher binding ability than that derived from algae. The fluorescence quenching results indicated that humic substances played a key role in the complexation between DOM and Cu(II) in the lake. However, because of the frequent breakout of algae blooms, protein-like matters are also main component like humic matters in Taihu Lake. Therefore, the metals bound by protein-like substances should be caused concern as protein-like substances in DOM were unstable and they will release bound metal when decomposed.

关键词： binding ability     dissolved organic matters     fluorescence quenching     complex capacity     Taihu Lake    

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通过DOM的光谱特性对长江源头典型高原深水湖泊进行评价

田林锋,胡继伟,李存雄,黄先飞,谢伟芳

《中国工程科学》 2010年 第12卷 第6期   页码 80-84

摘要：

天然溶解有机质（dissolved organic matter, DOM）研究在水体生态环境系统的修复研究中扮演着重要的角色，是近年来水环境研究领域的一个热点和难点

关键词： 天然溶解有机质     紫外―可见光谱     分子荧光光谱     相关性    

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Transformation of triclosan by a novel cold-adapted laccase from

Yuanyuan Shi, Deyang Kong, Jiayang Liu, Junhe Lu, Xiaoming Yin, Quansuo Zhou

《环境科学与工程前沿（英文）》 2017年 第11卷 第3期 doi: 10.1007/s11783-017-0927-5

摘要： This work investigated the transformation of triclosan (TCS) by laccase produced by a pathogen isolated from rotten tomato. The pathogen was characterized as sp. FQ, belonging to subphylum . The laccase exhibited cold-adaptation with relatively high activity at 20°C. The laccase could effectively transform TCS. Approximately 62% TCS could be removed at dose of 1.0 unit·mL in 120 min. The reaction rate appeared to be to the concentration of the substrate, suggesting the laccase activity remained stable during the reaction. Transformation products of TCS were analyzed by mass spectrometry and it was revealed that TCS dimers were formed via radical coupling pathways. During this process, laccase catalyzed oxidation of TCS to form a radical intermediate is the rate limiting step. However, this step can be reversed by humic acid. Overall, the laccase showed great potential in the treatment of phenolic contaminants. Since laccase is widely presented in natural environment, this study also revealed an important pathway involved in the transformation of phenolic contaminants in the environment.

关键词： Laccase     Botrytis cinerea     Triclosan     Transformation     Kinetics    

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FOOD SYSTEMS TRANSFORMATION: CONCEPTS, MECHANISMS AND PRACTICES

《农业科学与工程前沿（英文）》 2023年 第10卷 第1期   页码 1-3 doi: 10.15302/J-FASE-2023491

摘要： FOOD SYSTEMS TRANSFORMATION: CONCEPTS, MECHANISMS AND PRACTICES

关键词： TRANSFORMATION     SYSTEMS     FOOD     CONCEPTS     MECHANISMS    

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TRANSFORMATION OF FOOD SYSTEMS: HOW CAN IT BE FINANCED?

《农业科学与工程前沿（英文）》 2023年 第10卷 第1期   页码 109-123 doi: 10.15302/J-FASE-2023483

摘要：

● The analysis of financing for the transformation of food systems requires first a consideration of costs.

关键词： financial markets     food systems     development financing     consumer expenditures     public budgets     Sustainable Development Goals    

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The transformation of PAHs in the sewage sludge incineration treatment

Hui ZHANG,Le XU,Yifei ZHANG,Mengchan JIANG

《环境科学与工程前沿（英文）》 2016年 第10卷 第2期   页码 336-340 doi: 10.1007/s11783-014-0766-6

摘要： The release of pollutants from sewage sludge in the treatment process is a worldwide tricky problem in the field of sludge treatment. In this paper, the release and reaction between monomers of polycyclic aromatic hydrocarbons (PAHs) in the sewage sludge incineration treatment were studied based on simulated experiments. The result indicates that the transformation may occurre between monomers of PAHs during their release in the treatment. Over 90% of total PAHs in sewage sludge are released at the the temperature of 300°C–750°C. The possible transformation of Naphthalene to indeno(1, 2, 3-cd)pyrene was related to the temperature of the treatment system. Here, we showed that the output rate of transformation reactions for indeno(1, 2, 3-cd)pyrene is 94% at 300°C. These findings, by identifying corresponding treatment conditions as well as techniques, can help to understand the reactions and control real outputs of PAHs in the treatment process.

关键词： release of monomers     transformation of monomers     PAHs     sewage sludge     incineration treatment    

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面向数字化转型的“互联网 +”战略升级研究

何伟,张伟东,王超贤

《中国工程科学》 2020年 第22卷 第4期   页码 10-17 doi: 10.15302/J-SSCAE-2020.04.002

摘要：

“互联网 +”行动计划推出5年来，新一代信息技术创新进一步加快，经济社会数字化转型呈现诸多新特征，这就要求深入研究构建转型新体系和探索转型新路径，谋划“互联网 +”行动举措演进升级。本文遵循技术产业变革的客观规律，基于技术经济理论范式，着重分析了当前技术、应用和政策等层面数字化转型新态势和转型前沿实践探索。研究表明，当前数字化转型技术体系和技术能力日益完善，新的转型目标蓝图逐步显现，信息技术和实体经济融合进入新阶段，面临着重构数字化转型框架体系，强化转型关键要素、突破转型关键环节的重要任务。对此建议，在“互联网 +”行动后续政策设计、国家“十四五”规划制定的过程中，发掘数字化要素潜力，推动数字化转型生态建设，构建转型创新网络，升级“互联网 +”政策保障体系，推动经济社会数字化转型迈向更高发展水平。

关键词： 技术产业变革     数字化转型     互联网+     产业升级    

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Crystal-to-crystal transformation from the triclinic to the cubic crystal system by partial desolvation

Qianqian Guo, Irmgard Kalf, Ulli Englert

《化学科学与工程前沿（英文）》 2018年 第12卷 第3期   页码 433-439 doi: 10.1007/s11705-018-1743-6

摘要：

Diffusion reaction of the labile building block Mg(acacCN)2 (acacCN= 3-cyanoacetylacetonate) with silver salts leads to a series of solvated Mg/Ag bimetallic coordination polymers with composition [Mg(acacCN)3Ag]·solvent. Despite their common stoichiometry, the topology of these polymers depends on the solvent of crystallization. The two-dimensional coordination compound [Mg(acacCN)3Ag]·4CHCl3 in space group P1‾ is obtained as platelet-shaped crystals from a mixture of methanol and chloroform. When kept in the reaction mixture, these thin plates within one week convert to isometric tetrahedral crystals of the 3D network [Mg(acacCN)3Ag]·2CHCl3 in the cubic space group P213. The transformation reaction proceeds via dissolution and recrystallization. The co-crystallized solvent molecules play an important role for stabilizing the target structure: They subtend Cl···Cl contacts and interact via non-classical C–H···O hydrogen bonds with the coordination framework. In the new cubic coordination network, both Mg(II) and Ag(I) adopt octahedral coordination, with unprecedented face-sharing by bridging O atoms of three acetylacetonato moieties. Prolonged standing of [Mg(acacCN)3Ag]·2CHCl3 in the reaction medium leads to further degradation, under formation of [Ag(acacCN)].

关键词： ditopic ligand     substituted acetylacetone     desolvation     diffraction    

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Polymorphism and crystal transformation of penicillin sulfoxide

Dingding JING, Yongli WANG, Zhijian CHEN, Lina ZHOU, Jingkang WANG

《化学科学与工程前沿（英文）》 2011年 第5卷 第4期   页码 442-447 doi: 10.1007/s11705-011-1140-x

摘要： Penicillin sulfoxide is the intermediate for the synthesis of 7-amino-3-desacetoxycephalosporanic acid which is one of the most important nucleuses of cephalosporin antibiotic. In this contribution, two crystal structures of penicillin sulfoxide (forms I and II) were determined by X-ray diffraction, and their thermotropic properties were investigated by differential scanning calorimetry (DSC). Furthermore, the transformation of form II to form I was studied quantitatively by Raman spectroscopy, and its rates at different temperatures were determined. The results indicate that penicillin sulfoxide is more stable as form I, and the temperature plays an important role in the crystal transformation.

关键词： penicillin sulfoxide     crystallization     polymorphism     crystal transformation     Raman spectroscopy    

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A comprehensive simulation approach for pollutant bio-transformation in the gravity sewer

Nan Zhao, Huu Hao Ngo, Yuyou Li, Xiaochang Wang, Lei Yang, Pengkang Jin, Guangxi Sun

《环境科学与工程前沿（英文）》 2019年 第13卷 第4期 doi: 10.1007/s11783-019-1144-1

摘要：

A comprehensive pollutant transformation model for sewer systems is established.

The model comprises fermentation, sulfate reduction and ammonification processes.

Biochemical reactions related to distinct carbon sources are depicted in the model.

Pollutant transformation is attributed to different biochemical reaction processes.

关键词： Gravity sewer     Modeling     Pollutant transformation     Biochemical reaction process    

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Can industrial intelligence promote industrial transformation? ––Case of mining enterprises

Anlin SHAO

《工程管理前沿（英文）》 2017年 第4卷 第3期   页码 375-378 doi: 10.15302/J-FEM-2017108

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我国汽车产业转型升级研究

乔英俊,延建林,钟志华,赵俊玮

《中国工程科学》 2019年 第21卷 第3期   页码 41-46 doi: 10.15302/J-SSCAE-2019.03.001

摘要：

本文全面分析了当前我国汽车产业发展面临的新形势和未来发展的新趋向，研究提出了我国汽车产业转型升级的新内涵，即：新材料、新结构、新工艺、新装备、新能源、新功能、新模式，并分析比较了我国汽车产业转型升级的四种新路径，即自主技术创新、跨界联合发展、政策资源支持、创新商业模式，最后提出了相应的发展建议。

关键词： 汽车产业     转型升级     路径分析    

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Integrated risk assessment framework for transformation products of emerging contaminants: what we know

《环境科学与工程前沿（英文）》 2023年 第17卷 第7期 doi: 10.1007/s11783-023-1691-3

摘要：

● A better risk assessment can combine the improved non-target analysis method.

关键词： Risk assessment frameworks     Transformation products     Emerging contaminants     High-throughput toxicity screening     Water treatment    

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大直径盾构刀盘改造竖井施工技术

王振飞,何峰,贺善宁

《中国工程科学》 2010年 第12卷 第12期   页码 103-107

摘要：

以北京地下直径线盾构的刀盘改造竖井施工为例，针对复杂边界条件下大直径盾构刀盘改造异性结构竖井的设计及施工进行探讨，就如何保证竖井结构安全，同时又能合理协调盾构施工进行了实践探索，并给出了可靠的解决措施，取得了成功，为类似工程提供参考借鉴。

关键词： 大直径盾构     改造竖井     复杂条件    

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标题 作者 时间 类型 操作

on digestate humification and identification of substances governing the dissolved organic matter (DOM) transformation process

期刊论文

Quantitative characterization of Cu binding potential of dissolved organic matter (DOM) in sediment from

Yuan ZHANG,Yan ZHANG,Tao YU

期刊论文

通过DOM的光谱特性对长江源头典型高原深水湖泊进行评价

田林锋,胡继伟,李存雄,黄先飞,谢伟芳

期刊论文

Transformation of triclosan by a novel cold-adapted laccase from

Yuanyuan Shi, Deyang Kong, Jiayang Liu, Junhe Lu, Xiaoming Yin, Quansuo Zhou

期刊论文

FOOD SYSTEMS TRANSFORMATION: CONCEPTS, MECHANISMS AND PRACTICES

期刊论文

TRANSFORMATION OF FOOD SYSTEMS: HOW CAN IT BE FINANCED?

期刊论文

The transformation of PAHs in the sewage sludge incineration treatment

Hui ZHANG,Le XU,Yifei ZHANG,Mengchan JIANG

期刊论文

面向数字化转型的“互联网 +”战略升级研究

何伟,张伟东,王超贤

期刊论文

Crystal-to-crystal transformation from the triclinic to the cubic crystal system by partial desolvation

Qianqian Guo, Irmgard Kalf, Ulli Englert

期刊论文

Polymorphism and crystal transformation of penicillin sulfoxide

Dingding JING, Yongli WANG, Zhijian CHEN, Lina ZHOU, Jingkang WANG

期刊论文

A comprehensive simulation approach for pollutant bio-transformation in the gravity sewer

Nan Zhao, Huu Hao Ngo, Yuyou Li, Xiaochang Wang, Lei Yang, Pengkang Jin, Guangxi Sun

期刊论文

Can industrial intelligence promote industrial transformation? ––Case of mining enterprises

Anlin SHAO

期刊论文

我国汽车产业转型升级研究

乔英俊,延建林,钟志华,赵俊玮

期刊论文

Integrated risk assessment framework for transformation products of emerging contaminants: what we know

期刊论文

大直径盾构刀盘改造竖井施工技术

王振飞,何峰,贺善宁

期刊论文